Definder - what does the word mean?

What is head of the class?

A girl within a certain group of people (such as a high school class) who is known for administering blow jobs and/or other sexual favors. The term is a play on words, leading one to believe it is referring to the academic superior of a class.

Guy 1: "Man, Katie is such a bitch!"
Guy 2: "Yeah, she's the head of the class."

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head of the class - video